in discussion Organic Chemistry / Organic Synthesis Unsolved Problems » ORGANIC SYNTHESIS
![% Generated with LaTeXDraw 1.9.5 % Mon May 05 21:36:57 GMT+05:30 2008 % \usepackage[usenames,dvipsnames]{pstricks} % \usepackage{epsfig} % \usepackage{pst-grad} % For gradients % \usepackage{pst-plot} % For axes \scalebox{1} % Change this value to rescale the drawing. { \begin{pspicture}(0,-5.2051563)(9.780313,5.2051563) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(3.74,3.7401562)(0.54,-1.2598437) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(0.52,-1.2398437)(9.42,-3.0198438) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(9.42,-2.9998438)(3.74,3.7001562) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(3.72,3.7401562)(4.26,-1.9998437) \psline[linewidth=0.046cm](4.06,3.2201562)(3.92,2.9601562) \psline[linewidth=0.046cm](3.9,3.2001562)(4.12,3.0201561) \psline[linewidth=0.046cm](3.6,3.1201563)(3.32,2.7801561) \psline[linewidth=0.046cm](3.38,3.1001563)(3.6,2.8201563) \usefont{T1}{ptm}{b}{it} \rput(3.5621874,4.9801564){\Large Internal angle bisector theorom} \usefont{T1}{ptm}{m}{n} \rput(3.9865625,3.9301562){A} \usefont{T1}{ptm}{m}{n} \rput(9.627188,-2.9698439){B} \usefont{T1}{ptm}{m}{n} \rput(0.1871875,-1.4098438){C} \usefont{T1}{ptm}{m}{n} \rput(4.32,-2.2698438){D} \usefont{T1}{ptm}{m}{n} \rput(4.413594,-3.8098438){CAD = DAB} \psline[linewidth=0.0020cm,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4,doubleline=true,doublesep=0.12,doublecolor=White]{<->}(1.36,-4.779844)(2.68,-4.759844) \usefont{T1}{ptm}{m}{n} \rput(3.7323437,-4.549844){AC} \usefont{T1}{ptm}{m}{n} \rput(3.7165625,-5.049844){CD} \psline[linewidth=0.046cm](3.3,-4.759844)(4.2,-4.759844) \usefont{T1}{ptm}{m}{n} \rput(4.614844,-4.6298437){=} \usefont{T1}{ptm}{m}{n} \rput(5.52875,-4.529844){AB} \usefont{T1}{ptm}{m}{n} \rput(5.5401564,-4.989844){BD} \psline[linewidth=0.046cm](5.04,-4.739844)(5.92,-4.739844) \psline[linewidth=0.046cm,tbarsize=0.07055555cm 5.0]{|-|}(0.0,4.6401563)(7.08,4.6201563) \psline[linewidth=0.046cm](4.84,-3.4198437)(4.62,-4.0198436) \psline[linewidth=0.046cm](4.64,-3.9998438)(5.28,-3.9998438) \psline[linewidth=0.046cm](3.16,-3.3998437)(2.96,-3.9998438) \psline[linewidth=0.046cm](2.96,-3.9998438)(3.7,-3.9998438) \end{pspicture} }](/local--math/eqs/b914377e536db80af5e0cbc1f046b2a1.png)
![% Generated with LaTeXDraw 1.9.5 % Mon May 05 21:36:57 GMT+05:30 2008 % \usepackage[usenames,dvipsnames]{pstricks} % \usepackage{epsfig} % \usepackage{pst-grad} % For gradients % \usepackage{pst-plot} % For axes \scalebox{1} % Change this value to rescale the drawing. { \begin{pspicture}(0,-5.2051563)(9.780313,5.2051563) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(3.74,3.7401562)(0.54,-1.2598437) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(0.52,-1.2398437)(9.42,-3.0198438) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(9.42,-2.9998438)(3.74,3.7001562) \psline[linewidth=0.046cm,dotsize=0.07055555cm 2.0]{-o}(3.72,3.7401562)(4.26,-1.9998437) \psline[linewidth=0.046cm](4.06,3.2201562)(3.92,2.9601562) \psline[linewidth=0.046cm](3.9,3.2001562)(4.12,3.0201561) \psline[linewidth=0.046cm](3.6,3.1201563)(3.32,2.7801561) \psline[linewidth=0.046cm](3.38,3.1001563)(3.6,2.8201563) \usefont{T1}{ptm}{b}{it} \rput(3.5621874,4.9801564){\Large Internal angle bisector theorom} \usefont{T1}{ptm}{m}{n} \rput(3.9865625,3.9301562){A} \usefont{T1}{ptm}{m}{n} \rput(9.627188,-2.9698439){B} \usefont{T1}{ptm}{m}{n} \rput(0.1871875,-1.4098438){C} \usefont{T1}{ptm}{m}{n} \rput(4.32,-2.2698438){D} \usefont{T1}{ptm}{m}{n} \rput(4.413594,-3.8098438){CAD = DAB} \psline[linewidth=0.0020cm,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4,doubleline=true,doublesep=0.12,doublecolor=White]{<->}(1.36,-4.779844)(2.68,-4.759844) \usefont{T1}{ptm}{m}{n} \rput(3.7323437,-4.549844){AC} \usefont{T1}{ptm}{m}{n} \rput(3.7165625,-5.049844){CD} \psline[linewidth=0.046cm](3.3,-4.759844)(4.2,-4.759844) \usefont{T1}{ptm}{m}{n} \rput(4.614844,-4.6298437){=} \usefont{T1}{ptm}{m}{n} \rput(5.52875,-4.529844){AB} \usefont{T1}{ptm}{m}{n} \rput(5.5401564,-4.989844){BD} \psline[linewidth=0.046cm](5.04,-4.739844)(5.92,-4.739844) \psline[linewidth=0.046cm,tbarsize=0.07055555cm 5.0]{|-|}(0.0,4.6401563)(7.08,4.6201563) \psline[linewidth=0.046cm](4.84,-3.4198437)(4.62,-4.0198436) \psline[linewidth=0.046cm](4.64,-3.9998438)(5.28,-3.9998438) \psline[linewidth=0.046cm](3.16,-3.3998437)(2.96,-3.9998438) \psline[linewidth=0.046cm](2.96,-3.9998438)(3.7,-3.9998438) \end{pspicture} }](/local--math/eqs/b914377e536db80af5e0cbc1f046b2a1.png)
![% Generated with LaTeXDraw 1.9.5 % Mon May 05 16:21:07 GMT+05:30 2008 % \usepackage[usenames,dvipsnames]{pstricks} % \usepackage{epsfig} % \usepackage{pst-grad} % For gradients % \usepackage{pst-plot} % For axes \scalebox{1} % Change this value to rescale the drawing. { \begin{pspicture}(0,-3.853)(7.143,3.853) \psline[linewidth=0.046cm,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(5.7,1.97)(0.62,-2.23) \psline[linewidth=0.046cm,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(0.98,2.07)(6.24,-3.83) \psline[linewidth=0.046cm,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(3.76,2.33)(2.24,-3.03) \psframe[linewidth=0.046,dimen=middle,fillstyle=solid](2.62,3.83)(0.0,1.21) \psellipse[linewidth=0.046,dimen=middle,fillstyle=solid](5.64,-0.58)(1.48,2.63) \end{pspicture} }](/local--math/eqs/ef2472a77e5fd97634744b86fc711add.png)
![% Generated with LaTeXDraw 1.9.5 % Mon May 05 15:50:23 GMT+05:30 2008 % \usepackage[usenames,dvipsnames]{pstricks} % \usepackage{epsfig} % \usepackage{pst-grad} % For gradients % \usepackage{pst-plot} % For axes \scalebox{1} % Change this value to rescale the drawing. { \begin{pspicture}(0,-1.373)(1.4,1.373) \definecolor{color236}{rgb}{1.0,0.2,0.4} \psframe[linewidth=0.046,linecolor=color236,dimen=middle,fillstyle=solid](10.18,1.35)(0.0,-1.35) \psline[linewidth=0.046cm,linecolor=color236,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(1.7,1.05)(9.72,-0.31) \psline[linewidth=0.046cm,linecolor=color236,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(8.68,1.21)(1.28,-0.93) \psline[linewidth=0.046cm,linecolor=color236,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(5.72,1.17)(5.78,-0.75) \psline[linewidth=0.046cm,linecolor=color236,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(6.38,1.13)(4.96,-0.83) \psline[linewidth=0.046cm,linecolor=color236,arrowsize=0.05291667cm 2.0,arrowlength=1.4,arrowinset=0.4]{->}(5.12,0.99)(6.9,-0.63) \end{pspicture} }](/local--math/eqs/0896ce911491b91fd89071c08a8b6cd1.png)
(2.27,3.44) \psdiamond[linewidth=0.04,dimen=outer](5.06,0.11)(0.76,0.05) \psdiamond[linewidth=0.04,dimen=outer](5.23,-0.16)(2.05,2.0) \end{pspicture} }](/local--math/eqs/52450c5196c10bc8751e12733b04e2e2.png)
the new forum has been changed to [http://iit-redefined.theforum.name/index.php] . Join there immediately :) it has a lot of cool new features :)
then try and find out the answers to the questions asked :P :D if u want the answer :D
as i said it is not me who set the question…..
yes fixed that thanx :)
bcos u are refusing to answer certain necessary questions Huh? :D
Well, so do I. Ahhh! I know what mistake you are doing
Uncheck the option "Bind to IP" or like it.
why is everyone ignoring this question? :O
hey swadesi…… how do u know it is wrong? how can a chiral molecule posess a centre of symmetry? plz give examples….
why i always get logged on automatically
im not saying sanyal is better. wiki def has more named reactions but watever is given in sanyal is more detailed
dont tell me sanyal is better, ill kill you :D
which one, the one by sanyal.
da vinci, i knw dat is what base material claims and so do many other books but dat is wrong. actually only molecules with plane of symmetry are achiral. a chiral molecule may or may not possess a cenre of symmetry. but if u ever get that question in your base tests dont ever rite wat i told u. i've tried telling it to kerur and smh but sometimesteachers think they are infallible.
dei, is there a provision to automatically log on everytime you come to wikidot, im irritated to type the password everytime :D
$\mbox{To prove that} \ \frac{a+b}{2}-\sqrt{ab} \geq \frac{(a-b)^2(a+3b)(3a+b)}{8(a+b)(a^2+6ab+b^2)} \\ \\ \mbox{To prove that} \ (\sqrt{a}-\sqrt{b})^2 \geq \frac{(a-b)^2(a+3b)(3a+b)}{4(a+b)(a^2+6ab+b^2)} \\ \\ \mbox{writing} \ (a-b)^2 \ \mbox{as} \ (\sqrt{a}-\sqrt{b})^2*(\sqrt{a}+\sqrt{b})^2 \\ \\ \mbox{To prove that} \ 4(a^3+b^3+7ab(a+b))\geq (3(a^2+b^2)+10ab)(a+b+2\sqrt{ab}) \\ \\ \mbox{To prove that} \ a^3+b^3+15ab(a+b)\geq2\sqrt{ab}(3a^2+3b^2+10ab) \\ \\ \mbox{On squaring the above expression ..though slightly long but still worth it} \\ \\ \mbox{To prove that} \ a^6-6a^5b+15a^4b^2-20a^3b^3+15a^2b^4-6ab^5+b^6\geq 0 \\ \\ \mbox{To prove that} \ (a-b)^6\geq0 \\ \\ \mbox{which is always true} \\ \\ \mbox{Hence proved}$